PROCESSES AND PROPERTIES OF AIR
Dry-bulb, wet-bulb, dew-point temperatures, relative humidity-these terms
are so closely related that if two properties are known, all others shown
in the figure below may be read from the chart. When air is saturated,
dry-bulb, wet-bulb, and dew-point temperatures are identical. (See Example
2.)
Enthalpy of air for any given condition is the enthalpy at saturation
corrected by the enthalpy deviation due to the air not being in a saturated
state. The enthalpy (h) in Btu per pound of dry air is the enthalpy at
the saturation hwb plus the enthalpy deviation
hd See Example 2.
H + hwb + hd
If the air's moisture content increases or decreases in a psychometric
process, the heat added (q) or removed (-q) is the difference between
the enthalpy of the final or leaving air hla
and the initial or entering air hea minus
the enthalpy of the moisture (water in liquid or ice state) added hw
or rejected hw. See Examples 4 and 5.
q = hla - hea
- hw
The enthalpy of added or rejected moisture is shown in the small graphs
at the top of the chart.
Enthalpy of added or rejected moisture and enthalpy deviation are usually
omitted in applications not requiring precise results- for example, comfort
air conditioning. Errors due to omissions for wet-bulb temperatures below
32°F is much larger than for omissions above 32°F.
Sensible heat factor. This is part of certain calculations for
installing air condi-tioning equipment. A scale along the right side of
the figure in Example 4 below used with an origin at 80°F dry-bulb
temperature and 50 percent rh provide a reasonable heat factor value.
See Example 4.
Barometric pressures. In comfort air conditioning, a mercury reading
of one inch or less either above or below the standard 29.92 inches of
mercury is considered a standard reading.
When dry-bulb and dew-point temperatures are known for air at non-standard
barometric pressures, values of percent rh and grains of moisture per
cubic foot are correct on a standard chart. But for given dry-bulb and
wet-bulb readings at non-standard barometric pressures, all properties
must be corrected.
INTERPRETING THE AIR CONDITIONING CHARTS
Generally, in graphic presentations, humidifying is shown by an upward
line and dehumidifying is shown by a downward line.
Heating and cooling air without changes in moisture content involve
only a change in sensible heat and appear as a horizontal line, to right
or left respectively. Changes occur in dry-bulb, wet-bulb, rh, and enthalpy.
Specific humidity and dew-point temperature remain constant.
In heating and humidifying, both sensible heat and specific humidity
increase-shown as a line sloping upward and to the right. Changes occur
in dry-bulb, wet-bulb, dew-point temperatures, and enthalpy. A difference
in rh depends on the slope of the line.
For cooling and dehumidifying, both sensible heat and specific humidity
decrease, so the line slopes downward and to the left. Dry-bulb, wet-bulb,
dew-point temperatures, and enthalpy all change. Changes in rh are dependent
on the slope of the line.
Evaporative cooling refers to air brought in contact with spray
water at a temperature equal to the wet-bulb temperature of the air. The
process takes place upward along the wet-bulb line. As sensible heat of
the initial air vaporizes the water, the air's dry-bulb temperature falls.
The sensible heat used to vaporize the water enters the air as latent
heat in added vapor; thus no heat is added or removed. Wet-bulb temperature
remains constant. Dew-point temperature, rh, specific humidity, and enthalpy
increase.
(In most evaporative cooling installations, heat may be added or removed
during the process due to outside sources, this amount is usually negligible.)
In chemical dehydration, the air that contacts the chemical either adsorbs
or absorbs moisture from the air. Thus in this energy constant process,
heat is liberated and added to the air- and this amount is basically equal
to the latent heat of vaporization of the moisture removed. Indicated
by a downward sloping line approximating the wet-bulb line, the slope
of the chemical dehydration line may be either slightly greater or less
than the wet-bulb line, depending on if heat is stored, liberated, or
absorbed.
AIR CONDITIONING PROCESSES such as heating, cooling, humidifying and dehumidifying
may be shown graphically on the chart. See Figure 1.
EXAMPLE 1. Reading Properties of Air
| Given |
|
DB = 70°F |
|
% RH
DP |
|
Find:
|
Volume |
| WB = 60°F |
GR of moisture
per lb dry air
GR of moisture per cu. ft. |
Locate point of intersection on the chart of vertical line representing
70°DB and oblique line representing 60°WB. All values are read
from this point of intersection.
Interpolate between relative humidity lines on 70°DB line, read RH
= 56%.
Follow horizontal line left to saturation curve, read DP = 53.6°F.
Interpolate between lines representing cubic feet per pound of dry air,
read v = 13.53 cu ft.
Follow horizontal line to right, read grains of moisture per pound of
dry air, W=61.4 gr.
Grains of moisture per pound of dry air (61.4) divided by cubic feet per
pound of dry air (13.53) = 4.54 gr per cu ft.
EXAMPLE 2. Reading properties of Air
| Given |
|
DB = 50% |
|
DB
DP
Gr. of moisture per lb. dry air
Enthalpy |
|
Find:
|
| WB = 60°F |
Locate point of intersection on the chart of
50% RH line and oblique line representing 60°WB. All values are read
from this point.
Follow vertical line downward to dry-bulb temperature
scale, read DB = 71.9°F.
Follow horizontal line left to saturation curve,
read DP = 52.3°F.
Follow horizontal line to right, read grains
of moisture per pound of dry air, W = 58.4 gr.
Follow wet-bulb line to "Enthalpy at saturation"
scale and read Hwb = 26.46 Btu. Read enthalpy
deviation for point of intersection hd =
-.08 Btu. Enthalpy of air at given condition h= hwb
+ hd = 26.46 + (-.08) = 26.38 Btu per lb
of dry air.
EXAMPLE 3. Heating process
(no change in moisture content)

Locate the condition initial air on the chart.
Follow horizontal line to 75° DB.
Read:RH=15% : WB=51.5°F : DB=25.2°F.
Exact Solution - Head added:
Read enthalpy at saturation initial air hcwb
= 10.10 Btu
Read enthalpy deviation initial air hcd = 0.06
Btu
Enthalpy of initial air hca = hcwb
+ hcd = 10.10 + .06 = 10.16 Btu
Read enthalpy at saturation of final air hlwb
= 21.14 Btu
Read enthalpy deviation of final air hld
= 0.10 Btu
Enthalpy of final air hla = hlwb
+ hld = 21.14 + (-0.10) = 21.04 Btu
Heat added q = hla - hca
=21.04 - 10.16 = 10.88 Btu per lb of dry air
Approximate
Solution - Head added:
q = hlwb - hcwb
= 21.14 - 10.10 = 11.04 Btu per lb of dry air.
The approximate solution is 1.5% higher than exact solution.
EXAMPLE 4. Cooling and Dehumidifying Process
(a) Moisture rejected as water condensate

Locate initial and final conditions of air on chart.
Read: hcwb = 33.25 Btu
hlwb = 23.22Btu
hcd = -0.12 Btu
hld = -0.01 Btu
hca = 33.25 + (-0.12) = 33.13
Btu
hla = 23.22 + (-0.01) = 23.21
Btu
Read grains of moisture in initial air Wea=
84
Read
grains of moisture in final air Wla = 63 w
= Wla – Wea =
63 – 84 = 21 (moisture rejected)
Read enthalpy of rejected moisture (hw) from
diagrams at top of chart for 21 gr grains and 55 F = -0.8 Btu.
Exact Solution – Heat removed:
q = hla – hea
– hw = 23.21 – 33.13 – (0.08) =
-9.84 Btu per lb dry air.
Approximate Solution – Heat removed:
q = hlwb – hcwb
= 23.22 – 33.25 = -10.03 Btu per lb dry air.
Approximate solution is 1.9% higher than exact solution.
To determine Sensible Heat Factor, draw a line between initial and final
conditions. Draw a line parallel to this line from reference point (80
DB, 50RH) to Sensible Heat Factor scale, read SHF = 0.68.
EXAMPLE 5. Mixture of Air

Locate on chart conditions of inside and entering
air. Draw line connecting two points. Measure off distance equal to ¼
of line, starting from inside air condition. Point thus established represents
condition of mixture of inside and entering air.
Read properties of mixture:
DB = 80°F, WB = 65.6°F, h = 30.50 + (-0.11) = 30.39 Btu Moisture
content (W) = 71.3 gr per lb of dry air.
When air quantities being mixed are at widely
different temperatures, the above method is slightly in error. For exact
solution calculate properties of mixture on basis of specific humidity
and enthalpy.

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